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Hi

If you just want to play and learn, I suggest testing your LINUX setup in a Virtual Machine (Like VMWARE.com) which allows you run Linux inside a windows machine.

With Redhat versions, the PDF files that come with the release are very comprehensive, both for a GUI and command line. Release notes have answered about 40% of my questions and the rest in the search feature / knowledge base of the website of the OS.

You can start with a book on System / Network Administration if you are already familiar with the Linux Operating System. There is a lot of documentation and other reference material available on the net in the form of tutorials and guides. A book will however help you in learning things systematically. A good starting point is the Linux Documentation Project at http://www.tldp.org/.